Effect of annealing atmosphere on the structure and dielectric properties of unfilled tungsten bronze ceramics Ba4PrFe0.5Nb9.5O30

Unfilled tungsten bronze ceramics with the nominal formula Ba₄PrFe_0.5Nb_9.5O₃₀ were synthesized via the standard solid-state sintering route, and the effects of oxygen vacancies on the dielectric and electrical properties were investigated in addition to the structure. Room-temperature X-ray diffraction showed that the N₂-annealed sample had the largest cell volume. Low-temperature spectrum showed that N₂ annealing rendered the dielectric constant and dielectric loss more frequency dispersive, whereas O₂ annealing inhibited the frequency dispersion. The dc conductivity of all the samples originated from the electrons produced in the second ionization of oxygen vacancies and was most likely controlled by a mixed conduction mechanism of the electron and oxygen-vacancy ions. The N₂-annealed sample has the highest dc conductivity owing to its high concentration of oxygen vacancies. The broadening of the Raman lines and the decrease of Raman intensity for the N₂-annealed sample originated from a significant structural disorder. X-ray photoelectron spectra demonstrated that the increased oxygen vacancies caused by the change of valences of Fe and Pr ions contributed to the structural disorder.     

Advanced Functional Materials Constructed from Pillar[n]arenes

Pillar[n]arenes are new generation of supramolecular macrocyclic host, which exhibit excellent host−guest recognition properties. In the last decade, functional materials constructed from pillar[n]arenes have been attracted more and more attention and displayed outstanding characteristics, such as stimuli-responsiveness, self-healing and adaptability. In this mini-review, we provide a survey of the pillar[n]arene-based literatures covering light-harvesting systems, functional hydrogels, and solid materials. It is anticipated that more and more pillar[n]arenes-based advanced materials with multi-functional properties will appear in the near future.     

Synthesis of N-doped mesoporous carbons under different carbonization temperature and their application in supercapacitors

We have synthesized N-doped mesoporous carbon by the in-suit doping template method under the carbonized temperature of 900?°C. We found that the electrochemical performance of mesoporous carbon was enhanced by N-doping. So, we tried to increase the content of nitrogen to further optimize the electrochemical performance of the mesoporous carbon as electrode materials. During the process of synthesizing mesoporous carbon, the carbonized temperature played an important role in the formation of the carbon structure and its morphology, as well as in determining the content of nitrogen. We attained a considerable electrochemical performance enhancement by changing the carbonized temperature from 900 to 700?°C. We found the content of Nitrogen decreased with the increase of the carbonized temperature and the content of Nitrogen is 6.11% at 700?°C, 5.39% at 800?°C, 3.9% at 900?°C, respectively. The best electrochemical performance was observed in the product carbonized at 700?°C, which exhibited high specific capacitance (245.6 F/g at 0.5 A/g) and good cycle ability (more than 90% of the initial capacitance after 5000 cycles) in 6 M KOH electrolyte.     

Studying the influence of search rule and context shape in filtering impulse noise images with Markov chains

The paper presents an improved context-based denoising method for gray scale images affected by impulse noise. The proposed algorithm is using Markov chains to replace the detected noise with the intensity having the highest number of occurrences in similar contexts. The context of a noisy pixel consists in its neighbor pixels and is searched in a larger but limited surrounding area. We have analyzed different search methods and different context shapes. The experimental results obtained on the test images have shown that the most efficient model applies the search in form of   “*”  of contexts in form of   “+”. Besides the better denoising performance obtained on all the noise levels, the computational time has been also significantly improved with respect to our previous context-based filter which applied full search of full context. We have also compared this improved Markov filter with other denoising techniques existing in the literature, most of them being significantly outperformed.     

Microwave bandpass filter by feedback interference topology

This paper proposes a signal feedback interference topology to control the characteristics of a coupled line bandpass filter. Control is carried out by varying the ratio of the transmission line parameters of the forward and the feedback couplers. The topology produces a compact filter that does not require a complicated design or fabrication. The results of the insertion and return losses show that the feedback‐controlled design has desirable features in terms of the design frequency, fractional bandwidth, stopband rejection level, roll‐off rate and insertion loss. The test results of the fabricated prototype achieved good agreement with the simulation results of the ideal transmission line design model. Several microwave, modern wireless and mobile/satellite communication systems may benefit from such a filter design due to its compactness and flexibility.     

高泉背斜地层压力测井多参数综合解释与异常高压成因

目前国内外地层压力测井解释方法较多,但大多数方法基于欠压实沉积理论并局限于单一的地层岩性,尤其是针对盆地边缘山前深层构造,单一测井参数确定地层压力误差较大,且无法解释沉积压实机制以外的异常高压。为此,将多种异常高压机制相关的测井参数进行综合解释,建立适合山前复杂构造的地层压力测井多参数计算模型,评价准噶尔盆地南缘高泉背斜高探1井的地层压力剖面,其计算结果与钻井实测数据吻合,相对误差小于3.00%.同时,基于原始沉积加载—卸载过程力学原理,利用地层压力测井多参数分析判别出高泉背斜深层各层系异常高压的形成机制。